The Reds have made a perfect start to the season thanks to wins over Leeds and Chelsea, respectively.
While Arsenal are also yet to drop points after victories over Fulham and West Brom.
Jurgen Klopp’s men are favourites to come away with a victory at home, but the Gunners came out on top last time these two sides met in the Community Shield at Wembley in a clash that went all the way to a penalty shootout.
The two clubs are due to meet again on Thursday in the Carabao Cup.
Liverpool XI: Alisson; Robertson, van Dijk, Gomez, Alexander-Arnold; Keita, Wijnaldum, Fabinho; Mané, Firmino, Salah
Arsenal XI: Leno, Holding, David Luiz, Tierney, Bellerin, Elneny, Xhaka, Maitland-Niles, Willian, Lacazette, Aubameyang